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ABSTRACT Silver (Ag) is widely used for antimicrobial textiles due to its strong biocidal activity, but conventional Ag coating methods are often expensive and involve complex processing steps. In this study, we present a simple, solution‐based approach using polydopamine (PDA)‐assisted electroless Ag plating, which enables uniform Ag deposition on textiles with improved scalability. We systematically investigate the effects of pH, temperature, and oxygen concentration on the growth kinetics of Ag nanoparticles (NPs) during PDA‐assisted electroless Ag plating. Results show that elevated temperature (65°C), alkaline solution (pH = 10), and increased oxygen purging (50 sccm) each significantly accelerates Ag NP deposition, with coverage up to 56.69% and particle sizes up to 69.48 ± 14.89 nm. Optical and structural analyses confirmed enhanced PDA deposition as the key to expediting Ag NP growth on various textiles. Using this accelerated process, we developed a cost‐effective, 3D‐printed roll‐to‐roll system to scale up fabrication, achieving rapid and uniform Ag NP deposition. The resulting textiles exhibited superior antimicrobial properties, offering an affordable and effective solution for high‐performance hygiene applications. 

Abstract Soil physical and chemical properties play important roles in mass loss during soil–block tests but the relationship between soil properties and the decay caused by brown-rot and white-rot fungi remains unclear. The objective of this study was to investigate the soil effects on the decay resistance of pine (Pinus spp.) and poplar (Liriodendron tulipifera L.) blocks. The properties of soil from nine different sources (six from Idaho, one from Mississippi, one from Wisconsin, and one from Oregon) were characterized for soil texture, sieved bulk density, water-holding capacity, pH, organic matter, and carbon and nitrogen concentrations. The moisture content and mass loss of decayed wood samples after 8 weeks of fungal exposure were measured. At the end of the study, block moisture ranged from 30 to 200 percent and mass loss ranged from 20 to 60 percent. Despite using a range of soils, there were no direct correlations between soil properties and wood-block moisture content or mass loss. Moreover, among all the soil properties examined, no significant effect of a single soil property on wood-block moisture content and mass loss was measured. Instead, the combined effects of soil physical and chemical properties may interact to govern the decay of wood blocks in the laboratory soil–block test. 

The feasibility of using β-cyclodextrin (βCD) as an eco-friendly carrier of boric acid for the protection of strand-based wood composites against decay fungi was evaluated. The formation of a βCD–boric acid (βCD–B) complex was confirmed by the appearance of the boron–oxygen bond by using attenuated total reflection–Fourier transform infrared spectroscopy. Chemical shifts of around 6.25 and 1.41 ppm were also observed in 1H Nuclear Magnetic Resonance (NMR) and 11B NMR spectra, respectively. The βCD–B preservatives at two levels (5 and 10 wt.%) were uniformly blended with southern pine strands that were subsequently sprayed with polymeric methylene diphenyl diisocyanate (pMDI) resin. The blended strands were formed into a loose mat by hand and consolidated into 25 × 254 × 12 mm oriented strand boards (OSB) using a hot-press. The OSB panels were cut to end-matched internal bonding (IB) strength and fungal decay resistance test specimens. The vertical density profiles (VDPs) of the IB specimens were measured using an X-ray based density profiler and the specimens with statistically similar VDPs were selected for the IB and decay tests. The IB strength of the treated specimens was lower than the control specimens but they were above the required IB strength of heavy-duty load-bearing boards for use in humid conditions, specified in the BS EN 300:2006 standard. The reduced IB of preservative-treated OSB boards could be explained by the destabilized resin upon the addition of the βCD–B complex, as indicated by the differential scanning calorimetry (DSC) results. The resistance of the OSB panels against two brown-rot fungi (i.e., G. trabeum or P. placenta) was evaluated before and after accelerated leaching cycles. The treated OSBs exposed to the fungi showed an average mass loss of lower than 3% before leaching, while the untreated OSBs had 49 and 35% mass losses due to decay by G. trabeum or P. placenta, respectively. However, upon the leaching, the treatment provided protection only against G. trabeum to a certain degree (average mass loss of 15%). The experimental results suggest that protection efficacy against decay fungi after leaching, as well as the adhesion of the OSB strands, can be improved by increasing the amount of pMDI resin.